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                  <text>&lt;p style="margin-top: -1em; line-height: 1.2em;"&gt;The Alvin L. Young Collection on Agent Orange comprises 120 linear feet and spans the late 1800s to 2005; however, the bulk of the coverage is from the 1960s to the 1980s and there are many undated items. The collection was donated to Special Collections of the National Agricultural Library in 1985 by Dr. Alvin L. Young (1942- ). Dr. Young developed the collection as he conducted extensive research on the military defoliant Agent Orange. The collection is in good condition and includes letters, memoranda, books, reports, press releases, journal and newspaper clippings, field logs and notebooks, newsletters, maps, booklets and pamphlets, photographs, memorabilia, and audiotapes of an interview with Dr. Young.&lt;/p&gt;&#13;
&lt;p&gt;For more about this collection, &lt;a href="/exhibits/speccoll/exhibits/show/alvin-l--young-collection-on-a"&gt;view the Agent Orange Exhibit.&lt;/a&gt;&lt;/p&gt;</text>
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                <text>&lt;strong&gt;Corporate Author: &lt;/strong&gt;Pennsalt Chemicals Corporation, Pittsburgh, Pennsylvania</text>
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                <text>Graph: Viscosity in Centipoises - Relative to Water at 68 degree; with cover letter from W.C. Jackson to Raymond Hammon, November 30, 1964</text>
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                    <text>Item ID Number

°0284

Author
CorDOratO Author

Department of Defense

RODOrt/ArtiOlO TitlO Military Specification: Ferric Chloride, Anhydrous,
Crystalline, Technical, MIL-F-14580A

Journal/Book Titlo
Yoar

1965

Month/Day

Ma 11

Color

n

Number of Imarjes

°

DOSCrlptOD Notes

Found in a file Labeled: "Technical Manual-Use of
Herbicides + Federal Specifications for Herbicides";
supercedes MIL-F-14580(CE)

v

Monday, January 22, 2001

Page 284 of 341

�TOL-F11 May 1965

SUPERSEDING
MIL-F-1U580(CE)
18 July 1957
MILITARY SPECIFICATION
FERRIC CHLORIDE, ANHYDROUS, CRYSTALLINE, TECHNICAL
This specification is mandatory for use by all Departments
and Agencies of the Department of Defense.
1. SCOPE
1.1 This specification covers crystalline, anhydrous ferric chloride.
2. APPLICABLE DOCUMENTS
2.1 The following documents of the issue in effect on date of invitation for bids or request for proposal form a part of this specification to the extent specified herein:
SPECIFICATIONS
Federal
L-P-378

- Plastic Film (Polyethylene Thin Gage).

Military
JAN-D-195

- Drums, Steel, Calcium Carbide (100Pound Capacity).

STANDARDS
Military
MIL-STD-105
MIL-STD-129

- Sampling Procedures and Tables for
Inspection by Attributes.
- Marking for Shipment and Storage.

FSC 6810

�MIL-F-14580A
(Copies of specifications and standards required by suppliers in
connection with specific procurement functions should be obtained
from the procuring activity or as directed by the contracting officer.)
2.2 Other ..publications. The following documents form a part of
this specification to the extent specified herein. Unless otherwise
indicated, the issue in effect on date of invitation for bids or request for proposal shall apply.
AMERICAN PUBLIC HEALTH ASSOCIATION

Standard Methods for Examination of Water, Sewage, and Industrial
Wastes.
(Application for copies should be addressed to The American Public
Health Association, Inc., 1790 Broadway, New York, N. Y. 10019.)
3.

REQUIREMENTS

3.1 Chemical composition.
table I.

The ferric chloride shall conform to

Table I. Chemical composition
Requirement
Ferric chloride (FeCl-^)
Ferrous chloride (FeC^)
Water insolubles, as Fe20-a

Percent by weight
Minimum
Maximum

95-5

—
—

—

Test
Paragraph

4.4.2.4

1.0

4.4.2.3

4.0

4422
...

0.025
0-5
1.7
0.025
0.005
0.025

4.4.2.5
4.4.2.5
4.4.2.5
4.4.2.5
4.4.2.5
4.4.2.5

Deleterious ingredients
Lead
Copper
Fluoride
Arsenic
Selenium
Hexavalent chromium

—

�MIL-F-14580A
3 «2 Appearance . The color of the ferric chloride shall vary from
black to brown. A yellowish tinge within 1/4 inch of the seam of the
inner bag when packaged in 1-pound bags or within 1/4 inch of the top
when packaged as bulk in drums will be acceptable . The material shall
not be completely solidified or contain a large quantity of lumps that
are not easily broken. A hard layer that is easily broken and does
not extend more than 1/4 inch from the top will be acceptable for
material packaged as bulk in drums .
3-3 Quant ity . The ferric chloride shall be supplied in 1-pound
units or in bulk, as specified (see 6.2).
4.

QUALITY ASSURANCE PROVISIONS

4-1 Responsibility for inspection . Unless otherwise specified in
the contract or purchase order, the supplier is responsible for the
performance of all inspection requirements as specified herein. Except as otherwise specified, the supplier may utilize his own facilities or any commercial laboratory acceptable to the Government. The
Government reserves the right to perform any of the inspections set
forth in the specification where such inspections are deemed necessary
to insure supplies and services conform to prescribed requirements .
4.1.1 Component and material inspection . The supplier is responsible for insuring that components and materials used are manufactured,
examined, and tested in accordance with referenced specifications and
standards .
4.2 Classification of inspection.
as follows :

Inspection shall be classified

(a) Quality conformance inspection of the ferric chloride»
(see 4.3).
(b) Inspection of preparation for delivery (see 4.5).
4.3 Quality conformance inspection .
A

1 * shall consist of the ferric chloride offered for
°
acceptance at one time which has been produced by one manufacturer
under the same manufacturing conditions and with no change in materials
provided the operation is continuous. In the event that the process
is a batch operation, each batch shall constitute a lot (see 6.3).

�MIL-F-14580A

4.3.2 Sampling.
4.3.2.1 For eramination. Sampling for examination shall be in
accordance with MIL-STD-105.
4.3'2.2 For test. Sampling for tests shall be in accordance with
MIL-STD-105, inspection level 3-1. A specimen shall be removed from
each container in the sample and placed in a clean, dry container
labeled to identify the lot and the container from which it was taken.
4.4 Inspection procedure.
4.4.1 Examination.
Samples selected in accordance with 4.3.2.1
shall be examined for the following defects. AQL shall be 2.5 percent defective.
101. Color not as specified.
102. Lumps or hard surface not easily broken.
103. Yellowish tinge extends beyond 1/4 inch of inner seam
when packaged in 1-pound bags.
104. Yellowish tinge extends beyond 1/4 inch of top when
packaged as bulk.
4.4.2 Tests. Samples selected in accordance with 4.3.2.2 shall
be subjected to the tests specified in 4.4.2.2 through 4.4.2.5. Distilled water and reagent grade chemicals shall be used throughout
the tests. Where applicable, blank determinations shall be run and
corrections shall be applied where significant. Tests shall be conducted as follows. AQL shall be 1.0 percent defective.
4.4.2.1 Reagent solutions for tests.
4.4.2.1.1 Preventive solution. Dissolve 67 g of manganous sulfate
(MnSOi|.H20) in 500 to 600 ml of water; add 138 ml of phosphoric acid
(H^POli., specific gravity l.?0) and 130 ml of sulfuric acid (K^SOjj.,
specific gravity 1.84) and dilute to 1 liter. Cool to room temperature.
4 4 2 1 2 Mercuric chloride solution.
....
chloride (HgCl^T in 95 ml of water.

Dissolve 5 g of mercuric

4.4.2.1.3 Stannous chloride solution. Dissolve 150 g of iron-free
stannous chloride (SnCl2.2H20) in 1 liter of dilute hydrochloric acid
(333 ml of concentrated hydrochloric acid to 667 ml of water).

�4.U.2.1A PotassiiM permanganate solution (approximately 0.1 N).
Dissolve approximately 3.25 g of potassium permanganate (KMnOi^ in
approximately 1 liter of water, let stand in the dark for 2 weeks,
and filter, without washing, through a fritted glass crucible of
fine porosity or a Gooch crucible with an acid washed pad. Store
in a dark-colored glass-stoppered bottle. Standardize using
solium oxalate.
^.U.2.2 Water insoluble. Without undue exposure to air, transfer
4 to 5 g of ferric chloride to a tared weighing bottle, using a clean
paper funnel to prevent ferric chloride from coming in contact with
the ground joint. Stopper the bottle immediately, and reweigh the
bottle and contents. Wash the specimen into a 500-ml volumetric
flask with water, cool to approximately 25* C. ( 7 F.), fill the
7*
bottle to the mark with water and shake by hand. Allow the contents
to settle for about 10 minutes and then vacuum filter approximately
U25 ml of the solution through a tared Gooch crucible, containing
an acid washed asbestos pad, into a dry vacuum flask. Remove the
flask containing the filtrate, and save the filtrate for succeeding
analyses. Replace the vacuum flask with another vacuum flask, and
filter the remaining solution. Wash the flask with water, and add
washings to Gooch crucible. Repeat the washing procedure six times,
allowing the filter to pull dry between each washing. Wash the precipitate once with ethyl alcohol. Dry the crucible and precipitate
for 30 minutes at 100* C. ( 1 * F.), heat for 15 minutes at 600* C.
22
( 1 2 F.), cool in a desiccator to room temperature, and reweigh.
11*
All weighings are made to the nearest milligram. Calculate the percent water insolubles as FeO as follows :
Percent water insolubles

100 A
B

where A = Weight of precipitate (weight of crucible with asbestos
pad and precipitate minus weight crucible with asbestos
pad), and
B = Weight of sample (weight of weighing bottle and sample
minus weight of weighing bottle).
Nonconformance to table I shall constitute failure of this test.

�MIL-F-14580A

4.4.2.3 Ferrous chloride (FeCl^ Pipette 100 ml of filtrate (see
4.4.2.2) into a 250 ml Erlenmeyer flask, add 20 ml of preventive solution ( . . . . ) and titrate immediately to a 15-second pink end point
44211
with approximately 0.05 N potassium permanganate solution (50 ml of
approximately 0.1 N solution diluted to 100 ml with water). Run a
blank determination using water. Calculate the percent FeClc. as follows:
P
Percent ferrous iron
where A
B
C
D

m

(0.0558) (lOO) (A-B&gt; C
0.2 D

= ml of KMnO^ used in titration of sample,
= ml of KMnOii used in titration of blank,
= normality of KMnO^ solution,
* weight of sample used in water insoluble
determination (see 4. 4. 2. 2),

Percent FeClg = ( . ? (percent ferrous iron).
22)
Nonconformance to table I shall constitute failure of this test.
4 4 2 4 Ferric chloride ( e ^ . Pipette 50 ml of filtrate (see
...
FC)
4.4.2.2) into a 250 ml Erlenmeyer flask and add 5 ml of concentrated
hydrochloric acid. Place the flask on a hot plate and slowly evaporate the contents to 5 to 10 millillters. Add stannous chloride solution (see 4.4.2.1.3) dropwise to the hot filtrate until the iron is
reduced (color changes from yellow-red to a pale light green) . Use
diluted stannous chloride solution (l ml of stannous chloride solution to one ml of water) near the end point. Dilute the contents to
about 150 ml with water and cool. Add 10 ml of mercuric chloride solution (see 4 4 2 1 2 . The formation of a slight, white, silky pre....)
cipitate when the mercuric chloride solution is added indicates that
the proper amount of stannous chloride solution has been added. Discard the specimen if no precipitate (insufficient stannous chloride
solution has been added) or a heavy precipitate (excess of stannous
chloride solution has been added) is formed. Repeat the test. If
the proper amount of stannous chloride has been added, allow to stand
5 minutes, add 20 ml of preventive solution, and titrate immediately
to a 15-second pink end point with approximately 0.1 N potassium permanganate solution. Calculate the percent ferric chloride as follows:

�MIL-F-14580A

Percent total iron

(0.0558) (lOO) AB
0.1 C

•where A = ml of KMnO^ used in titration of sample,
B = normality of KMnO],. solution,
C *= the weight of the sample used in -water insoluble determination (see 4.4.2.2),
percent ferric iron = D-E,
where D = Percent total iron,
E = Percent ferrous iron, and
Percent ferric chloride = (2.95) (percent ferric iron.)
Nonconformance to table I shall constitute failure of this test.
4.4.2.5 Deleterious ingredients. Determine the tests for lead,
copper, fluoride, arsenic, selenuim, and hexavalent chromium in accordance with the appropriate method outlined in Standard Methods for the
Examination of Water, Sewage, and Industrial Wastes of the American
Public Health Association using filtrate (see 4 4 2 2 . Nonconform...)
ance to table I shall constitute failure of this test.
4.5 Inspection of preparation for delivery. The packaging, packing, and marking shall be inspected as follows.
4.5.1 Sampling for examination. Sampling for examination shall
be by lots and shall be in accordance with MIL-STD-105• Lot acceptance or rejection shall be based on an AQJj of 4.0 percent defective.
4.5«2 Examination. Samples selected in accordance with 4.5.1
.shall be examined for the following defects.
105.
16
0.
107.
18.
0.

Outer or inner bag missing when packaged in 1-pound quantities,
Ferric chloride or foreign matter in seam.
Width of seam is less than 3/8 inch.
Incomplete sealing (blisters or voids in seam).

�109.
110.
111.
112.
113.
Ilk.
115.
5.

Liner missing.
Liner not closed as specified.
Container not as specified.
Container damaged.
Holes in bags or liner.
Container closure not as specified.
Marking incorrect, missing, or illegible.

PREPARATION FOR DELIVERY

5.1 Packaging.
(see 6.271

Packaging shall be level A, B or C as specified

5-1-1 Precautions. The following precautions shall be taken when
packaging and packing the ferric chloride:
(a) The time that the ferric chloride is exposed to the atmosphere shall be kept to an absolute minimum.
(b) The air immediately above the loading hopper shall be heated
between 1^0* F. and 1 0 F., even though very low absolute
7°
humidity conditions are present. This method will extend
the time approximately 10 times that the ferric chloride
•in the hopper may be exposed to the atmosphere without caking.
5.1.2

Level A.

5.1.2.1 One-pound package. The ferric chloride shall be packaged
in 1-pound quantities in polyethylene inner bags, sealed, and each
sealed inner bag overpackaged in a polyethylene outer bag and the outer
bag sealed. The polyethylene inner and outer bags shall be fabricated
from polyethylene film conforming to L-P-378 and in the form of extruded lay-flat tubing without side seams. The end seams shall be
heat sealed not less than 3/8-inch wide with a smooth polished finish.
Wo type of parting agent shall be used in the fabrication of the seams.
The dimensions of the bags shall be as shown in table II.
Table II. Dimensions of Bags (inches)
Bag

Width

Inner

9-0.25

5 -0.25

0.0020

Outer

8

Length

10-0.25

6 to. 25

0.0060

Nominal thickness

�MIL-F-l*f580A
After filling the inner "bags and before heat sealing, precautions
shall be taken that no ferric chloride dust or foreign matter is on
the surfaces to be sealed. After filling and sealing, the inner bag
shall be immediately transferred to a separate area for packaging in
the outer bag.
5-1.2.2 Bulk quantity.
shall not be packaged.

Ferric chloride required in bulk quantity

5'1-3 Level B. The ferric chloride shall be packaged as specified
in 5-1-2.1 for 1-pound packages. Bulk quantity shall not be packaged.
5'1'^ Level C.«
The ferric chloride shall be packaged as specified
in 5.1.2,1 for 1-pound packages. Bulk quantity shall not be packaged.
5.2 Packing.
6.2).
5.2.1

Packing shall be level A, B, or C as specified (see

Level A.

5.2.1.1 One-pound bags. The ferric chloride, packaged as specified
in 5-1.2, shall be packed in 100-bag quantities in a 100-pound capacity
steel drum conforming to JAW-D-195* except the height dimension shall
be modified to contain the bags arranged in uniform layers. Each drum
shall be provided with a 5-mi-thick polyethylene bag liner fabricated
from material and heat sealed as specified in 5.1.2.1. The drum bag
liner shall be of sufficient length and width to form-fit inside the
drum with not less than a 3-inch length at the top for sealing. A
tag with identification marking shall be attached to the top of the
drum bag liner by covering the strings with a strip of the bag material
and heat sealing to the bag. The drum shall be closed in accordance
with the drum specification.
5.2.1.2 Bulk. One-hundred pounds of ferric chloride shall be
packed in a polyethylene lined drum as specified in 5.2.1.1.
5.2.2 Level B.
in 5-2.1.

The ferric chloride shall be packed as specified

5.2.3 Level C'.
in 5.2.1.

The ferric chloride shall be packed as specified

�MIL-F-14580A
5»3 Marking, In addition to any special marking required by the
contract or order, packages and shipping containers shall be marked
in accordance with MIL-STD-129.
6. NOTES
6.1 Intended use* The crystalline, anhydrous ferric chloride
covered by this specification is intended for use as a coagulant for
water purification.
6.2 Ordering data. Procurement documents should specify the
following:
(a) Title, number, and date of this specification.
(b) Whether ferric chloride shall be packaged in 1-pound bags
or in bulk (see 3 3 .
.)
(c) Level of packaging and level of packing required (see 5.1
and 5«2). Level B preservation and packaging is intended
to provide limited but economical protection and should be
specified only when it is determined the ferric chloride
will be held in covered storage approximately 1 year from
date of initial preservation and packaging.
6*3 Batch. A batch is defined as that quantity of material which
has been subjected to some unit chemical or physical mixing process
intended to make the final product substantially uniform (see 4 3 1 .
..)
Custodians:
Army - MO(ERDL)
Navy - SH
Air Force - 68
Review activities;
Army - MU, MD
Navy - YD, MC
Air Force - 68
Us er activitie s;
Navy - SH

10

Preparing activity;
Army - MO(ERDL)
Project No. 6810-0243

�I

SPECIFICATION ANALYSIS SHEET

Form Approved
Budget Bureau No. 119-B.Q04

INSTfattlONS
This sheet is to be filled out by personnel either Government or contractor, involved in the use of the spec
ification in procurement of products for ultimate use by the Department of Defense. This sheet is provided for ob
taining information on the use of this specification which will insure that suitable products can be procured with
minimum amount of delay and at the least cost. Comments and the return of this form will be appreciated. Fold o
SPECI Fl CATION

MIL-F-1^580A - Ferric Chloride, Anhydrous, Crystalline, Technical

ORGANIZATION (Of ,ubmitter)

1 CITY AND STATE

CONTRACT NO.

QUANTITY OF 1 TEMS PROCURED

DOLLAR AMOUNT
f

MATERIAL PROCURED UNDER A
1 1 DIRECT GOVERNMENT CONTRACT
F~l SUBCONTRACT
1. HAS ANY PART OF THE SPECIFICATION CREATED PROBLEMS OR REQUIRED INTERPRETATION IN PROCUREMENT USE?
A. G I V E PARAGRAPH NUMBER AND WORDING.

B. RECOMMENDATIONS FOR C O R R E C T I N G THE D E F I C I E N C I E S .

2. COMMENTS ON ANY SPECIFICATION REQUIREMENT CONSIDERED TOO R I G I D

3.

IS THE S P E C I F I C A T I O N R E S T R I C T I V E ?
L^ YES

i~l NO

IF "YES") IN WAT

WAY!

4. REMARKS (Attach any per tin en t da ta uhich nay be of use in up roving this sped ficat ion. If there are additional papers, a t t a c h to font and place both in an envelope addressed to preparing act ivity )

SUBMITTED BY (Printed or typed name and activity)

DATE

D — 63. 913 ARMY — FORT BELVOIR, VA.

�FOLD

DEPARTMENT OF THE ARMY
U. S. ARMY MOBILITY EQUIPMENT CENTER
RESEARCH, DEVELOPMENT AND ENGINEERING DIRECTORATE
ATTN: SMOFB-RDE-KX
FORT BELVOIR, VIRGINIA 22060

POSTAGE AND FEES PAID
DEPARTMENT OF THE ARMY

OFFICIAL BUSINESS

DEPARTMENT OF THE ARMY
U. S. ARMY MOBILITY EQUIPMENT CENTER
RESEARCH, DEVELOPMENT AND ENGINEERING DIRECTORATE
ATTN: SMOFB-RDE-KX
FORT BELVOIR, VIRGINIA 22060

FOLD

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&lt;p&gt;For more about this collection, &lt;a href="/exhibits/speccoll/exhibits/show/alvin-l--young-collection-on-a"&gt;view the Agent Orange Exhibit.&lt;/a&gt;&lt;/p&gt;</text>
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&lt;p&gt;For more about this collection, &lt;a href="/exhibits/speccoll/exhibits/show/alvin-l--young-collection-on-a"&gt;view the Agent Orange Exhibit.&lt;/a&gt;&lt;/p&gt;</text>
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&lt;p&gt;For more about this collection, &lt;a href="/exhibits/speccoll/exhibits/show/alvin-l--young-collection-on-a"&gt;view the Agent Orange Exhibit.&lt;/a&gt;&lt;/p&gt;</text>
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&lt;p&gt;For more about this collection, &lt;a href="/exhibits/speccoll/exhibits/show/alvin-l--young-collection-on-a"&gt;view the Agent Orange Exhibit.&lt;/a&gt;&lt;/p&gt;</text>
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&lt;p&gt;For more about this collection, &lt;a href="/exhibits/speccoll/exhibits/show/alvin-l--young-collection-on-a"&gt;view the Agent Orange Exhibit.&lt;/a&gt;&lt;/p&gt;</text>
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