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                    <text>Item D Number

°1795

Author

Young, Alvin L.

Corporate Author
Rmort/ArOdfl TlflB Typescript: Use of Herbicides in South Vietnam, 1961nivui i/ni uuu MUD 1971 _ June 14 _ 1983

Journal/Book Title
Year

000

°

Month/Day
Color

n

Number of images

9

DeSCTlpton NOtBS

Alvin L Youn

9filed tnis item under "Vietnam Veterans
Twin Study." Typescript is a synopsis of information
from Chapters I and III of The Toxicology,
Environmental Fate, and Human Risk of Herbicide
Orange and Its Associated Dioxin (see Item 1165).

Wednesday, July 11, 2001

Page 1796 of 1870

�USE OF HERBICIDES IN SOUTH VIETNAM, 1961-1971*
Alvin L. Young
MAJOR, USAF, Ph.D.
Herbicides used in support of tactical military operations in South Vietnam
from 1961 to 1971 are today, twelve years after the last herbicide mission, the
center of intense scientific debate involving not only medical but also legal,
political and ecological issues. This paper reviews the historical and operational
concepts and some potential human exposure considerations involving the military
use of herbicides in the Southeast Asian Conflict.

Synthesis technology, efficacy data, and field application techniques were
developed for the two major phenoxy herbicides, 2,4-dichlorophenoxyacetic acid
(2,4--D) and 2,4,5-trichlorophenoxyacetic acid (2,4,5-T) during World War II at Fort
Detrick, Frederick, Maryland. Following World War II, the commercial use of these
two "synthetic" organic herbicides revolutionized American agriculture. In 1950,
more than 10 million pounds of these materials were used annually for weed and
brush control in the United States. By 1960, in excess of 36 million pounds were
used.
In May 1961, the Office of the Secretary of Defense requested the Fort
Detrick personnel to determine the technical feasibility of defoliating jungle
vegetation in the Republic of Vietnam. By early fall, 1961, 18 different aerial
spray tests (defoliation and anticrop) had been conducted with various formulations
of commercially-available herbicides. The choice of these herbicides was based
upon the chemicals that had had considerable research, proven performance, and
practical background at that period in time. Also, such factors as availability in
large quantity, costs, and known or accepted safety in regard to their toxicity to
humans and animals was considered, The results of these tests were that
significant defoliation and anticrop effects could be obtained with two different
mixtures of herbicides. The first was a mixture of the n-butyl esters of 2,4-D and
2,^,5-T and the iso-butyl ester of 2,4, 5-T. This mixture was code-named "Purple".
The second "military" herbicide was code-named "Blue" and consisted of the acid
and sodium salt of cacodylic acid. The colored bands which were painted around
the center of the 55~gailon drums served as aid to the identification by support
personnel.
.
*
The first shipment of Herbicides Purple and Blue was received at Tan Son
Nhut Air Base, Republic of Vietnam, on 9 January 1962. These were the first
military herbicides used in Operation RANCH HAND, the tactical military project
for the aerial spraying of herbicides in South Vietnam. Two additional phenoxy
herbicide formulations were received in limited quantities in South Vietnam and
A synopsis of Information from Chapters I and III of The Toxicology,
Environmental Fate, and Human Risk of Herbicide Orange and Its Associated
Dioxin, Air Force Technical Report OEHL-TR-78-92, USAF Occupational and
Environmental Health Laboratory, Brooks Air Force Base, Texas. (Authors:
A. L. Young, 3. A. Calcagni, C. E. Thalken, and 3. W. Tremblay) 1978.
6-14-83

�evaluated during the first two years of Operation RANCH HAND. These were
code-named Pink and Green. By January 1965, two additional military herbicides,
code-named Orange and White, had been evaluated and brought into the spray
program. Herbicide Orange replaced all uses of Purple, Pink, or Green, and
eventually became the most widely used military herbicide in South Vietnam. The
composition of the three major herbicides used in South Vietnam were as follows:
1.

Herbicide Orange

Orange was a reddish-brown to tan colored liquid soluble in diesel fuel
and organic solvents, but insoluble in water. One gallon of Orange
theoretically contained 4.21 pounds of the active ingredient of 2,4--D and 4.41
pounds of the active ingredient of 2,4,5-T. Orange was formulated to contain
a 50:50 mixture of the ri-butyl esters of 2,4~D and 2,4,5-T. The percentages
of the formulation typically were:
n-butyl ester of 2,4-D
.free acid of 2,4-D
n-butyl ester of 2,4,5-T
free acid of 2,4,5-T
inert ingredients (e.g.,
butyl alcohol and ester
moieties)
2.

49.49
0.13
48.75
1.00
0.62

Herbicide White

White was a dark brown viscous liquid that was soluble in water but
insoluble in organic solvents and diesel fuel. One gallon of White contained
0.54 pounds of the active ingredient of 4-amino~3,5,6~trichloropicolinic acid
(picloram) and 2.00 pounds of the active ingredient of 2,4-D. White was
formulated to contain a 1:4 mixture of the triisopropanoamine salts of
picloram and 2,4-D. The percentages of the formulation were:
triisopropanolamine salt of picloram 10.2
triisopropanolarnine salt of 2,4~D
39.6
inert ingredient (primarily the
50.2
solvent triisopropanolamine)
3.

Herbicide Blue

.

•*

Blue was a clear yellowish-tan liquid that was soluble in water, but
insoluble in organic solvents and diesel fuel. One gallon of Blue contained
3.10 pounds of the active ingredient hydroxydimethyarsine oxide (cacodylic
acid). Blue was formulated to contain cacodylic acid (as the free acid) and
the sodium salt of cacodylic acid (sodium cacodylate). The percentages of
the formulation were:
cacodylic acid
sodium cacodylate
surfactant
sodium chloride
6-14-83

4.7
26.4
3.4
5.5

�water
antifoam agent

39.5
0.5

As previously noted, not all of the herbicides used in South Vietnam were
used throughout the entire 10 years (1962-1971) encompassed by the Department of
Defense defoliation program. In addition, 2,4»5-T formulations used early in the
program are believed to have contained higher levels of the toxic contaminant
TCDD (2,3,7,8~tetrachlorodibenzo-p-dioxin or "dioxin") than did the formulations
used in later years. The three time periods shown in Table 1 can be differentiated
on the basis of specific herbicides used and the mean dioxin content.
TABLE 1
THE DIFFERENTIATION OF THREE TIME PERIODS DURING THE US MILITARY
DEFOLIATION PROGRAM IN SOUTH VIETNAM AND MEAN DIOXIN CONTENT

PERIOD

HERBICIDES USED
- (CODE NAMES)

MEAN DIOXIN CONTENT
(PARTS PER MILLION)*

January 1962 June 1965

Purple, Pink, Green
Blue

July 1965June 1970

Orange
White, Blue

2+
0

July 1970 October 1971

White, Blue

0

*
**

32**
0

Found only in 2,4,5-T containing formulations.
Value based on analyses of five samples.
Orange based on the analyses of 488 samples.

Herbicide Orange was the most extensively used herbicide in South Vietnam.
Orange accounted for approximately 10.7 million gallons of the total 17.7 million
gallons of herbicide used (Table 2). It was used from mid-1965 to i June 1970.
However, as stated in Table 2, Orange was not the only 2,^5-T containing
herbicide used in the defoliation program. Small quantities of Purple, Pink, and
Green, all containing 2,4,5-T were used from 1962 through mid-1965. In subsequent
sections of this document, the term "Herbicide Orange" will refer to all of the
2,4,5-T containing herbicides used in Vietnam (Purple, Pink, Green, and Orange).

6-14-83

�TABLE 2
NUMBER OF GALLONS OF MILITARY HERBICIDE PROCURED BY THE
US DEPARTMENT OF DEFENSE AND DISSEMINATED IN SOUTH VIETNAM
DURING JANUARY 1962 - OCTOBER 1971

Code Name

Herbicide

Orange

2,4-D; 2,4,5-T

1965-1970*

White

2,4-D; Picloram

1965-1971**

Blue

Cacodylic Acid

1962-1971**

Purple

2,4-D; 2,4,5-T

1962-1965

Pink

2,4,5-T

1962-1965

Green

2,4,5-T

1962-1965

Quantity

Period of Use

Total
*
First fixed-wing spray mission of Herbicide Orange April 16, 1970; last
helicopter spray mission of Herbicide Orange June 6, 1970.
**

Last fixed-wing mission January 9, 1971; all herbicides under US control
stopped October 1971.

Use Patterns of Individual Herbicides
Each of the three major herbicides (Orange, White, and Blue) had specific
uses. Ninety-nine percent of Herbicide White was applied in defoliation missions.
It was not recommended for use on crops because of the persistence of Picloram in
soils. Because the herbicidal action on woody plants was usually slow, full
defoliation did not occur for several months after spray application, thus, it was
an ideal herbicide for use in the inland forests in areas where defoliation was not
immediately required, but where it did occur it would persist longer than if the
area were sprayed with Orange or Blue.
Herbicide Blue was the herbicide of choice for crop destruction missions
involving cereal or grain crops. Approximately 50 percent of all Blue was used in
crop destruction missions in remote or enemy controlled areas with the remainder
being used as a contact herbicide for control of grasses around base perimeters.
Ninety percent of all Herbicide Orange was used for forest defoliation and it
was especially effective in defoliating mangrove forests. Eight percent of
Herbicide Orange was used in the destruction of broadleaf crops (beans, peanuts,
6-14-83

�ramie, and root or tuber crops). The remaining 2 percent was used around base
perimeters, cache sites, waterways, and communication lines.
Table 3 shows the number of acres sprayed with herbicides in South Vietnam
within the three major vegetationai categories.
TABLE 3
THE NUMBER OF ACRES TREATED IN SOUTH VIETNAM, 1962-1971,
WITH MILITARY HERBICIDES WITHIN THE THREE MA3OR
VEGETATIONAL CATEGORIES
Vegetationai Caafegory

Areas Treated*

Inland forest

2,670,000

Mangrove forests

318,000

Cultivated crops

260,000

Total

3,2*8,000

"Areas receiving single or multiple coverage.
Certain portions of South Vietnam were more likely to have been subjected to
defoliation. Herbicide expenditures for the four Combat Tactical Zones of South
Vietnam are shown in Table 4. These data were obtained from the HERBS tape (a
computer listing of all herbicide missions in South Vietnam from 1965 through
1971). Total volume is in close agreement with the actual procurement data shown
in Table 2.
TABLE 4
US HERBICIDES EXPENDITURES IN SOUTH VIETNAM, 1962-1971:
A BREAKDOWN BY COMBAT TACTICAL ZONE*
ical Zones

Orange

Herbicide Expenditure fgalions)
White
Blue
''*

CTZ I

.2,250,000

363,000

298,000

CTZ II

2,519,000

729,000

473,000

5,309,000

3,719,000

294,000

1*227^000
11,305,000

*35jpOO
5,246,000

62*000
1,127,000
J7,678A000

CTZ III

des Saigon)

CTZ IV

Subtotals
Grand Total

6-14-83

�In addition to herbicides, numerous other chemicals were shipped to South
Vietnam in 55-gallon drums. These included selected fuel additives, cleaning
solvents, cooking oils, and a variety of pesticides. The insecticide Malathion was
widely used for control of mosquitoes and at least 400,000 gallons of it were used
from 1966 through 1970. In addition, much smaller quantities of Lindane and DDT
were used in ground operations throughout the war in Southeast Asia. The
distribution of the herbicides within Vietnam after their arrival did not occur
randomly. About 65 percent was shipped to the 20th Ordnance Storage Depot,
Saigon, and 3.5 percent was shipped to the 511th Ordnance Depot, Da Nang.

Numerous aircraft were used in the air war in Vietnam, but only a few of
these aircraft were used for aerial dissemination of herbicides. The "work horse"
of operation RANCH HAND was the C-123, "Provider". This cargo aircraft was
adapted to receive a modular spray system for internal carriage. The module (the
A/A 45 Y-l) consisted of a 1,000-gallon tank pump, and engine which were all
mounted on a frame pallet. An operator's console was an integral part of the unit,
but was not mounted on the pallet. Wing booms (1.5 inches in diameter, 22 feet
long) extended from the outboard engine nacelles toward the wing tips. A short
tail boom (3 inches in diameter, 20 feet long) was positioned centrally near the aft
cargo door. Each aircraft normally had a crew of three men: the pilot, co-pilot
(nagivator), and flight engineer (console operator). During the peak activity of
RANCH HAND operations (1968-1969), approximately 30 U C-123K aircraft were
employed. However, many other squadrons of non-RANCH HAND C-123 aircraft
were routinely used throughout South Vietnam in transport operations.
The control of malaria and other rnosquito-borne diseases in South Vietnam
necessitated an extensive aerial insecticide application program. From 1966
through 1972, three C-123 aircraft were used to spray Malathion, an
organophosphate insecticide. These aircraft could be distinguished from the
Herbicide-spraying aircraft because they were not camouflaged. These aircraft
routinely sprayed insecticide adjacent to military and civilian installations, as well
as in areas where military operations were in progress, or about to commence.
Approximately 10 to 12 percent of all herbicides used in South Vietnam were
disseminated by helicopter or ground application equipment. Generally, helicopter
crews were not assigned to herbicide spray duties on a full-time basis and rotated
the spraying duties with other mission requirements. The military UH-1 series of
helicopters, deployed by the Air .Force, the Army, and Navy units, generally
sprayed the herbicides.
The most common spray system used was the
AGRINAUTICS unit. This unit was installed in or removed from the aircraft in a
matter of minutes because it was "tied down" to installed cargo shackles and
aircraft modifications were not required for its use. The unit consisted of a 200gallon tank and a collapsible 32-foot spray boom. The unit was operated by manual
controls to control the flow valve and a windmill brake. Generally, each helicopter
had three crew members.
A summary of the aircraft used in herbicide and insecticide operations is
shown in Table 5.

6-14-83

.6

�TABLE 5
US MILITARY AIRCRAFT USED IN THE DISSEMINATION OF
HERBICIDES AND INSECTICIDES IN SOUTH VIETNAM

Aircraft

Camouflaged

Chemical Disseminated

UC-123/UC-123K

Yes

All Herbicides

UC-123K

No

Malathion

Yes

Orange, Blue

Helicopter
Air Force UH-1
Army UH-1B/UH-1D
Navy UH/iE
Various ground delivery systems were also used in South Vietnam for control
of vegetation in limited areas. Most of these units were towed or mounted on
vehicles. One unit that was routinely used was the Buffalo turbine. It developed a
wind blast with a velocity up to 150 MPH at 10,000 ft^/minute volume. When the
herbicide was injected into the air blast, it was essentially "shot" at the foliage.
The buffalo turbine was useful for roadside spraying and applications of perimeter
defenses. The herbicides of choice in these operations were Blue and Orange.
Table 6 reviews the pertinent chemical and physical characteristics of
Herbicide Orange. Table 7 reviews both the application parameters of the spray
system used in the UC-123K aircraft and the characteristics of the spray itself.
Generally, herbicides were sprayed in the early morning or late afternoon, so as to
minimize the effects of air movement on particle dispersion.

6-14-83

�TABLE 6
PERTINENT CHEMICAL AND PHYSICAL CHARACTERISTICS
OF HERBICIDE ORANGE
Formulation Concentrated

(8.6 Ib ai/gai)*

Water Insoluble

Density = 1.28

Vapor Pressure

3.6 x 10~* mm Hg at 30°C

NBE** 2,4-D

: 1.2 x 1Q~4

NBE 2,4,5-T

: 0.* x 10-*

TCDD

:

Viscous

1 x 10-*

.

40 centipoises at 20°C

Noncorrosive to rnetal
Deleterious to paints, rubber, neoprene
Long Shelf life
*
**

Pounds active ingredient (2,4™D and 2,4,5-T) per gallon.
NBE - Normal Butyl ester.
TABLE 7
APPLICATION PARAMETERS AND SPRAY CHARACTERISTICS OF THE
C-123 MODULAR INTERNAL SPRAY SYSTEM

Aircraft speed
Aircraft altitude
Tank volume
Spray time
Particle size:
100 microns:
1.9%
100-500 microns:
76.2% -.
500 microns:
21.9%
87% impacted within 1 min
13% drifted or volatilized
Mean particle volume
Spray swath
Mean deposition
Total area/tank
Knots indicated air speed

6-14-83

130 K1AS*
150 feet
1,000 gallons
3.5-4 minutes

0.61 microliters
260 + 20 feet
3 gallons/acre
340 acres

�SUMMARY
The choice of herbicides used in South Vietnam in Operation RANCH HAND,
1962-1971, was based upon those herbicides that had been widely used in world
agriculture, shown to be effective in controlling a broad spectrum of vegetation,
and thought to be safe to humans and animals. The major herbicides used in South
Vietnam were the phenoxy herbicides 2,4-D and 2,4,5-T. These two herbicides
were formulated as the water insoluble esters and code-named by the military as
Purple, Orange, Pink and Green. A water soluble amine formulation of 2,4~D was
used in Herbicide White. Two other herbicides were extensively used by the
military, picloram (in White) and cacodylic acid (in Blue).
An estimated 107 million pounds of herbicides were aerially disseminated on
3 million acres in South Vietnam from January 1962 through October 1971.
Approximately 94 percent of all herbicides sprayed in Vietnam were 2,4-D (56
million pounds or 53 percent of total) or 2,4,5-T (44 million pounds or 41 percent of
total). The 44 million pounds of 2,4,5-T contained an estimated 368 pounds of the
toxic contaminant 2,3,7,8-tetrachlorodibenzo-p-dioxin (TCDD or dioxin). Ninetysix percent of all 2,4,5-T was contained in Herbicide Orange; the remaining 4
percent in Herbicides Green, Pink and Purple. However, Herbicides Green, Pink
and Purple contained approximately 40 percent of the estimated amount of TCDD
disseminated in South Vietnam. Green, Pink and Purple were sprayed as defoliants
on Jess than 90,000 acres from 1962 through 1964, a period when only a small force
of US military personnel were in South Vietnam. Ninety percent of all the
Herbicide Orange (containing 38.3 million pounds of 2,4,5-T and 203 pounds of
TCDD) were used in defoliation operations on 2.9 million acres of inland forests
and mangrove forests of South Vietnam.

6-14-83

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                  <text>&lt;p style="margin-top: -1em; line-height: 1.2em;"&gt;The Alvin L. Young Collection on Agent Orange comprises 120 linear feet and spans the late 1800s to 2005; however, the bulk of the coverage is from the 1960s to the 1980s and there are many undated items. The collection was donated to Special Collections of the National Agricultural Library in 1985 by Dr. Alvin L. Young (1942- ). Dr. Young developed the collection as he conducted extensive research on the military defoliant Agent Orange. The collection is in good condition and includes letters, memoranda, books, reports, press releases, journal and newspaper clippings, field logs and notebooks, newsletters, maps, booklets and pamphlets, photographs, memorabilia, and audiotapes of an interview with Dr. Young.&lt;/p&gt;&#13;
&lt;p&gt;For more about this collection, &lt;a href="/exhibits/speccoll/exhibits/show/alvin-l--young-collection-on-a"&gt;view the Agent Orange Exhibit.&lt;/a&gt;&lt;/p&gt;</text>
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                  <text>&lt;p style="margin-top: -1em; line-height: 1.2em;"&gt;The Alvin L. Young Collection on Agent Orange comprises 120 linear feet and spans the late 1800s to 2005; however, the bulk of the coverage is from the 1960s to the 1980s and there are many undated items. The collection was donated to Special Collections of the National Agricultural Library in 1985 by Dr. Alvin L. Young (1942- ). Dr. Young developed the collection as he conducted extensive research on the military defoliant Agent Orange. The collection is in good condition and includes letters, memoranda, books, reports, press releases, journal and newspaper clippings, field logs and notebooks, newsletters, maps, booklets and pamphlets, photographs, memorabilia, and audiotapes of an interview with Dr. Young.&lt;/p&gt;&#13;
&lt;p&gt;For more about this collection, &lt;a href="/exhibits/speccoll/exhibits/show/alvin-l--young-collection-on-a"&gt;view the Agent Orange Exhibit.&lt;/a&gt;&lt;/p&gt;</text>
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&lt;p&gt;For more about this collection, &lt;a href="/exhibits/speccoll/exhibits/show/alvin-l--young-collection-on-a"&gt;view the Agent Orange Exhibit.&lt;/a&gt;&lt;/p&gt;</text>
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